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dc.contributor.authorCaligari Conti, Malcolm-
dc.contributor.authorMallia, Bertram-
dc.contributor.authorSinagra, Emmanuel-
dc.contributor.authorSchembri-Wismayer, Pierre-
dc.contributor.authorBuhagiar, Joseph-
dc.contributor.authorVella, Daniel A.-
dc.identifier.citationCaligari Conti, M., Mallia, B., Sinagra, E., Schembri Wismayer, P., Buhagiar, J., & Vella, D. (2019). The effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloys. Heliyon, 5(9) doi:10.1016/j.heliyon.2019.e02522en_GB
dc.description.abstractCurrent trends in the biodegradable scaffold industry call for powder metallurgy methods in which compression cannot be applied due to the nature of the scaffold template itself and the need to retain the shape of an underlying template throughout the fabrication process. Iron alloys have been shown to be good candidates for biomedical applications where load support is required. Fe–Mn alloys were researched extensively for this purpose. Current research shows that all metallurgical characterisation and corrosion test on Fe–Mn and Fe–Mn–Ag non pre-alloyed powder alloys are performed on alloys which are initially pressed into greens and subsequently sintered. In order to combine the cutting-edge field of biodegradable metallic alloys with scaffold production, metallurgical characterisation of pressed and non-pressed Fe, Fe–Mn and Fe–Mn–Ag sintered elemental powder compacts was carried out in this study. This was performed along with determination of the corrosion rate of the same alloys in in vitro mimicking solutions. These solutions were synthesised to mimic the osteo environment in which the final scaffolds are to be used. Both pressed and non-pressed alloys formed an austenite phase under the right sintering conditions. The corrosion rate of the non-pressed alloy was greater than that of its pressed counterpart. In a potentiodynamic testing scenario, addition of silver to the alloy formed a separate silver phase which galvanically increased the corrosion rate of the pressed alloy. This result wasn't replicated in the non-pressed alloys in which the corrosion rate was seen to remain similar to the non-silver-bearing alloy counterparts.en_GB
dc.publisherElsevier Ltden_GB
dc.subjectMaterials scienceen_GB
dc.subjectPhysical biochemistryen_GB
dc.subjectMusculoskeletal systemen_GB
dc.subjectBiodegradable productsen_GB
dc.subjectPowder metallurgyen_GB
dc.titleThe effect of alloying elements on the properties of pressed and non-pressed biodegradable Fe–Mn–Ag powder metallurgy alloysen_GB
dc.rights.holderThe copyright of this work belongs to the author(s)/publisher. The rights of this work are as defined by the appropriate Copyright Legislation or as modified by any successive legislation. Users may access this work and can make use of the information contained in accordance with the Copyright Legislation provided that the author must be properly acknowledged. Further distribution or reproduction in any format is prohibited without the prior permission of the copyright holder.en_GB
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