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Title: Blocked shape memory effect in negative Poisson’s ratio polymer metamaterials
Authors: Boba, Katarzyna
Bianchi, Matteo
McCombe, Greg
Gatt, Ruben
Griffin, Anselm C.
Richardson, Robert M.
Scarpa, Fabrizio
Hamerton, Ian
Grima, Joseph N.
Keywords: Foamed materials
Shape memory effect
Issue Date: 2016-07
Publisher: American Chemical Society
Citation: Boba, K., Bianchi, M., McCombe, G., Gatt, R., Griffin, A. C., Richardson, R. M., ... Grima, J. N. (2016). Blocked shape memory effect in negative Poisson’s ratio polymer metamaterials. ACS Applied Materials & Interfaces, 8(31), 20319-20328.
Abstract: We describe a new class of negative Poisson’s ratio (NPR) open cell PU–PE foams produced by blocking the shape memory effect in the polymer. Contrary to classical NPR open cell thermoset and thermoplastic foams that return to their auxetic phase after reheating (and therefore limit their use in technological applications), this new class of cellular solids has a permanent negative Poisson’s ratio behavior, generated through multiple shape memory (mSM) treatments that lead to a fixity of the topology of the cell foam. The mSM-NPR foams have Poisson’s ratio values similar to the auxetic foams prior their return to the conventional phase, but compressive stress–strain curves similar to the ones of conventional foams. The results show that by manipulating the shape memory effect in polymer microstructures it is possible to obtain new classes of materials with unusual deformation mechanisms.
Appears in Collections:Scholarly Works - FacSciChe
Scholarly Works - FacSciMet

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