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|Title:||A new two-step synthesis of 2-alkylated 1, 4-diketones and α-alkylated γ-keto esters|
|Citation:||Ballini, R., Bosica, G., Petrelli, L., & Petrini, M. (1999). A new two-step synthesis of 2-alkylated 1, 4-diketones and α-alkylated γ-keto esters. Synthesis, 1999(07), 1236-1240.|
|Abstract:||2-Alkylated 1,4-diketones and a-alkylated g-keto esters can be easily prepared by a two-step procedure which involves first the conjugate addition of a nitroalkane to an enedione derivative in acetonitrile with DBU as base, followed by chemoselective hydrogenation of the C–C double bond (H2, 10% Pd/C) of the Michael adduct, obtained after elimination of nitrous acid.|
|Appears in Collections:||Scholarly Works - FacSciChe|
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