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https://www.um.edu.mt/library/oar/handle/123456789/133548| Title: | N,n-dialkylcarbamato lanthanide complexes, a series of isotypical coordination compounds |
| Authors: | Baisch, Ulrich Dell’Amico, Daniela Belli Calderazzo, Fausto Labella, Luca Marchetti, Fabio Merigo, Alessandra |
| Keywords: | Magnetic susceptibility Coordination compounds Organometallic chemistry Carbamates X-ray crystallography Magnetic susceptibility |
| Issue Date: | 2004 |
| Publisher: | Wiley-VCH Verlag GmbH & Co. KGaA |
| Citation: | Baisch, U., Belli Dell’Amico, D., Calderazzo, F., Labella, L., Marchetti, F., & Merigo, A. (2004). N, N‐Dialkylcarbamato Lanthanide Complexes, a Series of Isotypical Coordination Compounds. European journal of inorganic chemistry, 2004(6), 1219-1224. |
| Abstract: | The preparations of the N,N-dialkylcarbamato complexes with analytical formulae [Ln(O2CNR2)3] (Ln = Pr, Nd, Eu, Gd, Ho, Er, Yb, Lu, R = iPr; Ln = Nd, Eu, Gd, R = Bu; Ln = Nd, R = Et), using [LnCl3(ether)x] (ether = THF or dimethoxyethane, DME), NHR2, and CO2 are reported. X-ray diffraction of the diisopropylcarbamato derivatives, including a reinvestigation of [Yb4(O2CNiPr2)12], showed these complexes to be tetranuclear and isotypical over a range of 12 atomic numbers. The lanthanide contraction has been evaluated based on the lengths of four different types of Ln−O bond. |
| URI: | https://www.um.edu.mt/library/oar/handle/123456789/133548 |
| ISSN: | 10990682 |
| Appears in Collections: | Scholarly Works - FacSciChe |
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| N,N_Dialkylcarbamato_Lanthanide_Complexes,_a_Series_of_IsotypicalCoordination_Compounds(2004).pdf Restricted Access | 122.84 kB | Adobe PDF | View/Open Request a copy |
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